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Weird Battery Cable Corrosion ?

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Old Feb 15, 2012 | 09:25 AM
  #1  
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Weird Battery Cable Corrosion ?

Have had 2 red top Optimas in the X since 2005. Both batteries are fine and turn the 6.0 over with no problem, even in cold weather (20° - 30°F). However, I have noticed significant corrosion buildup (green stuff) on the passenger side battery negative terminal over the last 6 months. All of the other 3 terminals look like they came from the factory. Will probably replace the cable. If that much corrosion is on the surface, I would asssume some has crept into the cable to terminal connection and will degrade the passenger side battery performance.

Anyone else had this problem? What was the fix?

DSMMH
 
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Old Feb 15, 2012 | 03:51 PM
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My drivers side does this too. I'm thinking of replacing the cables and coating everything in grease.
 
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Old Feb 15, 2012 | 04:06 PM
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I like the red stuff in a spray can - CRC Battery Terminal Protector. Seems to work well.
 
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Old Feb 15, 2012 | 04:15 PM
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Sometimes this is a sign of one battery starting to get weak
My advise would be to remove them, charge them separately and have them load tested.
In the mean time wash the battery box/ clamps with water and baking soda
Grease or wd40 may help protect it from moisture, but not from the battery sulfating
 
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Old Feb 15, 2012 | 04:29 PM
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It can also be the sign of a bad ground.
 
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Old Feb 15, 2012 | 04:51 PM
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Originally Posted by npccpartsman
It can also be the sign of a bad ground.
Where would you check for this? Both battery's load test fine for me.
 
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Old Feb 15, 2012 | 05:41 PM
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Originally Posted by Unrealo4
Where would you check for this? Both battery's load test fine for me.
Everywhere the ground cables bolt to the truck, which is multiple places on a Superduty.

I have that stupid corrosion issue on my drivers negative cable and my grounds are fine. Batteries both load test good. I put on the corrosion inhibitor to fix it and no more issues as of now (knock on wood).
 
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Old Feb 15, 2012 | 06:11 PM
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Clean the battery terminals, coat with di-electric grease, thin coat, install anti-corrosion pads, connect and spray the red crc terminal protection stuff. Works like a charm. No matter what you do, always check terminals when checking oil. Good pro-active maint.
 
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Old Feb 15, 2012 | 08:06 PM
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I believe the case to post seal sometimes allows gas to escape and corode the cable clamp. Once anything corodes it is more prone to corode again thereafter. I find battery cable grease to be more effective than sprays. Installing the felt disks and greasing clamps before corosion starts seems to be the best approach.
 
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Old Feb 15, 2012 | 10:47 PM
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With corrosion on a single post, I'd really suspect a leaking battery. Optimas are AGM with a gel, if I remember correctly, so it would seem odd for acid to be leaking out, but perhaps there is some evaporation occuring and evaporated battery acid is leaking out that terminal.

There is a cleaner spray that has an acid detector in it. You might try it. This is the stuff I used, it foams up when you spray it on, and the foam turns purple if acid is present.

http://www.amazon.com/CRC-05023-Tech...gy_auto_text_b
 
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Old Feb 16, 2012 | 06:01 AM
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Originally Posted by jjaz43
Sometimes this is a sign of one battery starting to get weak
My advise would be to remove them, charge them separately and have them load tested.
In the mean time wash the battery box/ clamps with water and baking soda
Grease or wd40 may help protect it from moisture, but not from the battery sulfating
I agree this could be an early sign of the battery getting weak. After all they are 7 years old. Will do a load test this weekend.

Am getting a new ground cable today.

Optimas are gel batteries and do not corrode the clamps and battery boxes like lead/acid batteries. That is one of the reasons I buy Optima batteries.

Thanks for the feedback!

DSMMH
 
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Old Feb 16, 2012 | 07:08 AM
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Optimas are gel batteries and do not corrode the clamps and battery boxes like lead/acid batteries. That is one of the reasons I buy Optima batteries.

Yet yours as you describe it are.
This has me curious, so I went to Optima's website
Optima Battery FAQ - Frequently Asked Questions
When used with a properly regulated constant voltage charging system (such as an alternator) the OPTIMA will usually not emit hydrogen gas. However, gassing can occur when charging at higher voltage levels or in extreme high temperature conditions. In automotive applications this typically will not happen if the alternator/regulator stay below 15 volts.
And
A gel battery design is typically a modification of the standard lead-acid automotive or marine battery. A gelling agent is added to the electrolyte to reduce movement inside the battery case. Many gel batteries also use one way valves in place of open vents, which helps the normal internal gasses to recombine back into water in the battery, reducing gassing.

An OPTIMA battery is not a "gel" battery or regular flooded acid battery. An OPTIMA is a Spiralcell AGM battery.
 
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Old Feb 16, 2012 | 11:53 AM
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Originally Posted by jjaz43
Optimas are gel batteries and do not corrode the clamps and battery boxes like lead/acid batteries. That is one of the reasons I buy Optima batteries.

Yet yours as you describe it are.
This has me curious, so I went to Optima's website
Optima Battery FAQ - Frequently Asked Questions
When used with a properly regulated constant voltage charging system (such as an alternator) the OPTIMA will usually not emit hydrogen gas. However, gassing can occur when charging at higher voltage levels or in extreme high temperature conditions. In automotive applications this typically will not happen if the alternator/regulator stay below 15 volts.
And
A gel battery design is typically a modification of the standard lead-acid automotive or marine battery. A gelling agent is added to the electrolyte to reduce movement inside the battery case. Many gel batteries also use one way valves in place of open vents, which helps the normal internal gasses to recombine back into water in the battery, reducing gassing.

An OPTIMA battery is not a "gel" battery or regular flooded acid battery. An OPTIMA is a Spiralcell AGM battery.
Agree, but none of the other terminals in the X show any corrosion at all. Also there are no tell tale moisture trails, as you would see with lead/acid batteries, on any of my Optimas.

I have two marine Optimas in my Sonic go fast boat, one Red Top Optima in my ZO6 and one marine Optima in my other smaller fishing boat. None of those show any signs of corrosion. I would certainly expect to see it on the marine Optimas but they are all clean.

npccpartsman has the same issue, except on the other side, and he has done all of the stuff you previously recommended. Not sure if he has lead/acid or AGM batteries.

Going to change ground cable tomorrow and see what happens.

DSMMH
 
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Old Feb 16, 2012 | 03:15 PM
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As Da Bees said, the source of your corrosion is probably hydrogen gas seeping up from the post.
I prefer to have cables made or make your own when possible because I hate the tiny hardware the factory uses.
The finest I have seen is after crimping the clamp or lug on, heat it up with a butane torch and fill the end with soldier to seal corrosion out.
Then finish it with heat shrink over the top
 
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Old Feb 16, 2012 | 03:28 PM
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Originally Posted by DSMMH
Agree, but none of the other terminals in the X show any corrosion at all. Also there are no tell tale moisture trails, as you would see with lead/acid batteries, on any of my Optimas.

I have two marine Optimas in my Sonic go fast boat, one Red Top Optima in my ZO6 and one marine Optima in my other smaller fishing boat. None of those show any signs of corrosion.

npccpartsman has the same issue, except on the other side, and he has done all of the stuff you previously recommended.



DSMMH
All of which tells us there is something different about 1 out of 4 terminals on both yours and partsman's batteries. The question seems to be"what could be different that results in corosion"? 1 out of 4 is clue #1. Your discription of the corosion as being green is clue #2. There are no other place we know of on vehicle that has similar corosion(or is there). That is clue #3.
I submit as possiable answers,#1 Defect #2 acid #3 Battery spicific
That is a lot of comments on a vehicle I have never even saw driving by,much less examined but you asked for opinions.
As far as changing the cable to see what happens,may I also offer somthing regarding that? While you are at it I suspect you will be cleaning all terminals. Why not also switch sides with the batteries? If the problem then shows up on drivers side negative cable,that pretty much seals the deal. Good luck
 

Last edited by da-bees; Feb 16, 2012 at 03:30 PM. Reason: Add the word "also" switch
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