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I have some similar going on. A/c works great cruising down the road but when Im accelerating harder it’s switches to defrost and blows out heat in the back of the van but still cool air on the dash. I have a 2009 ford e350 econoline passenger van
It is cause by either a crack in the vacuum hose running from the intake manifold to the vacuum reservoir, or the check valve in that same vacuum line is no good.