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If that Bronc has a vacuum-controlled valve that shuts off coolant flow to the heater core when you select MAX A/C, it or its hose may be leaking; if so, you lose vacuum and the airflow goes to Default (defrost).
By Federal law when something breaks in a heating system it is suppose to default to defroster mode. So, the first place to look in any vehicle is the vacuum system. If the vacuum fails, a spring pulls the vent closed to default to defrost.
On your vehicle, just remove the radio to get at the lines.
What you can do is buy a cheap brake bleeder and by connecting it to various lines you can change the modes. The valve on most vehicles is a round four post disc.
> Or is there something else (cheaper) to start looking at?
I think on the 1993 5.0/5.8L they still used a plastic can? I would put my brake bleeder there and force a good vacuum with the a/c switched to panel (vent) and see if they stayed there. You just might have a minor hose leak or cannister leak.
Rezvani's Latest Post-Apocalytic Monster Is a Ford F-150 Raptor Underneath
Slideshow: Called the Fortress, the 850-horsepower pickup combines Raptor underpinnings with military-inspired features, survival equipment, and a starting price of $285,000.