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drench the rusted bolt with either wd40 or some liquid wrench and wait at least 20 minutes then b4 you try to turn it loose give it a couple of medium type taps on top of the bolt then slowly turn with gradual increasing strength.
Exhaust bolts rusting on 1997 F150 4x4. I could not get the
exhaust bolt out of the exhaust mantifold, the only way to do
this is to take the mantifold off the head and take it to machine shop.
V8man
Usually (if you have access to the bolt) heating the manifold with a torch will usually help to get it loose. These newer vehicles are built with everything packed so tight, you may not be able to get a torch in there without burning up something else.