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I don't believe that's possible in Outlook. I know there is a program that can monitor what ever email port that your computer uses (I think it's 20) and gives you a copy of whatever is sent.
Yeah, Outlook Express is extremely vulnerable to hackers, viruses, and anything else bad. Normal Microshaft programming. I would switch over to mozilla if I were you www.mozilla.com It's easier to use and doesn't use as much resources to run.
I know when you send mail that a copy went into the sent folder. I wanted something so I can verify that my server works for every email I send in stead of outlook saying it was sent. If I was able to set it up to automatically set it up to send me a BCC on every email then I will jnow that the messege went somewhere.
I'm new to Outlook, I used to have Poco Mail. It is one of those client you have to buy. You would be amazed what I was able to do with that client. I would still have them if I didn't lose the program in a crash & I am to cheap to buy it again.