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Part of the problem is that the paint was fairly fresh when the water or whatever got on it. Most paints, even if usable in a few hours or days, do not fully cure for some time after that--weeks or even over a month. During that time, they are more susceptible to water and chemicals.
But, from the looks of that spot, there could very well have been something under that particular area that is off-gassing under the paint. An old oil or chemical spill, or that spot didn't get etched, there are any number of possibilities, including what Dennis said about the floor not being completely dry. Usually, a moisture test should be done in several areas before painting. There are several methods of that, the most common of which is to tape down a 2'x2' square of clear plastic (4 mil or thicker) for 24 hours and see if moisture forms underneatch the plastic. If it does, the concrete is either too green or has too much moisture under it and coming through.
Rezvani's Latest Post-Apocalyptic Monster Is a Ford F-150 Raptor Underneath
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