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Of late, it's been "Hello" by Evanescence. "Tears in Heaven" by Eric Clapton sounds great, too.
Also:
Deftones- Rx Queen
STP- Interstate Love Song
Sara Maclachlan- darn near anything
Social Distortion- self titled
All these songs/albums just plain relax me. Sara's are so beautifully recorded and her voice is straight from heaven. Amy Lee's voice (Evan...) is great, too.
Anything from Tool, Metallica, STP, Pink Floyd, AC/DC and lots of country. I cannot say there is one song, I really enjoy anything I listen to on it, but "Prodigy - Serial Thrilla" sounds damn good.
"Hell Yeah" By Montgomery Gentry is frickin awesome. When I feel like singin, anything trace adkins will do, but I'm Tryin is my signature. Can't beat some Tim McGraw either.