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Not sure why there are 2 units behind the muffler. Maybe there is a special emissions requirement in your area. Wish I could be more help, do both units look the same/similar or are there distinct differences? The cat is usually the closest to the engine on the exhaust. At least in a traditional set up with a cat and muffler.
rla2005 is correct, they are both catalytic converters. IIRC the first one is for HC and CO. The second one, which I believe has the air tube going to it, is for NOx.
Well that's what I need to know! I guess at this point I'll try to measure pressure at the secondary air injection fitting between the two units, and see if its less or the same as what I had at the O2 sensor.