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I doubt they reduce much engine compartment heat...they are primarily for looks. They won't rust like painted steel headers and are used on many fancy hot rods to keep things looking nice.
To get heat out of the engine comparment you need to wrap the headers with heat tape.
Do ceramic headers really reduce heat in the engine compartment and by how much.
I remember when we were searching for ceramic engine blocks and ceramic headers etc, because it didn't matter how hot they got, they would never warp! But I am thinking you are speaking of ceramic coating like what powder coating is. Where fine particles are sprayed onto a metalic object and held on with a magnetic bond until put in Kiln and melting the ceramic right into bonding with the metal. Making a bulletproof surface that always looks bright, shiny and new????