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What is the best way to clean the engine for painting? I have used Naptha to clean the oil off various parts but it seems to leave some kind of film that paint may not stick to.
After cleaning the engine with your choice of cleaner use 3m wax and grease remover. This is used by paint shops as the final prep before painting. It removes any wax, grease, and other residue from othe cleaners. It has a slower evaporation rate than naphtha, acetone, and thinners. I put the wax and grease remover in a spray bottle soak the engine down and start wiping, continue reapplying until your rag remains clean.
I used to use TSP quite a bit with good results. A little elbow grease too. I think dawn is probably the best though. I have a small jug by the sink to clean up with after wrenchin'.